There is no single answer for setting zones except for assuring that
life safety is the #1 priority
Zones will rarely be perfect circles.
The Hot Zone may be elongated to mactch a wind direction and speed.
Irregular shapes may be needed to account for flowing or potentially flowing fuel.
Example:
The fill points for fuel delivery trucks at this location are loacted at the South portion of the parking lot.
Leaking fuel would flow downhill, around the curb, into a drain which runs uder the road and into a ditch beside of Athen's Pizza.
A situationally aware firefighter/commander should be looking at the topography and for drains & ditches.... anywhere the fuel spill will flow to.